PTHH: \(2NaOH+CuSO_4\rightarrow Na_2SO_4+Cu\left(OH\right)_2\downarrow\)

a) Ta có: \(n_{CuSO_4}=\dfrac{320\cdot20\%}{160}=0,4\left(mol\right)=n_{Cu\left(OH\right)_2}\) \(\Rightarrow m_{Cu\left(OH\right)_2}=0,4\cdot98=39,2\left(g\right)\)

b) Theo PTHH: \(n_{NaOH}=2n_{CuSO_4}=0,8mol\) \(\Rightarrow m_{ddNaOH}=\dfrac{0,8\cdot40}{10\%}=320\left(g\right)\)

c) Theo PTHH: \(n_{Na_2SO_4}=n_{CuSO_4}=0,4mol\) \(\Rightarrow m_{Na_2SO_4}=0,4\cdot142=56,8\left(g\right)\)

Mặt khác: \(m_{dd}=m_{ddNaOH}+m_{ddCuSO_4}-m_{Cu\left(OH\right)_2}=600,8\left(g\right)\)

\(\Rightarrow C\%_{Na_2SO_4}=\dfrac{56,8}{600,8}\cdot100\%\approx9,45\%\) 

Ta có: \(C_{\%_{KOH}}=\dfrac{m_{KOH}}{112}.100\%=56\%\)

=> m_KOH = 62,72(g)

=> \(n_{KOH}=\dfrac{62,72}{56}=1,12\left(mol\right)\)

a. PTHH: 2KOH + MgCl₂ ---> Mg(OH)₂↓ + 2KCl

Theo PT: \(n_{Mg\left(OH\right)_2}=\dfrac{1}{2}.n_{KOH}=\dfrac{1}{2}.1,12=0,56\left(mol\right)\)

=> \(m_{Mg\left(OH\right)_2}=0,56.58=32,48\left(g\right)\)

b. Theo PT: \(n_{MgCl_2}=n_{Mg\left(OH\right)_2}=0,56\left(mol\right)\)

=> \(m_{MgCl_2}=0,56.95=53,2\left(g\right)\)

=> \(C_{\%_{MgCl_2}}=\dfrac{53,2}{200}.100\%=26,6\%\)

a)b)c)d) mBaCl2=150.16,64%=24,96g

=>nBaCl2=0,12 mol

mH2SO4=100.14,7%=14,7g=>nH2SO4=0,15mol

     BaCl2       + H2SO4 =>BaSO4    +2HCl

Bđ: 0,12 mol;    0,15 mol

Pứ: 0,12 mol=>0,12 mol=>0,12 mol=>0,24 mol

Dư:                   0,03 mol

Dd ban đầu chứa BaCl2 0,12 mol và H2SO4 0,15 mol

Dd A sau phản ứng chứa HCl 0,24 mol và H2SO4 dư 0,03 mol

mHCl=0,24.36,5=8,76g

mH2SO4=0,03.98=2,94g

Kết tủa B là BaSO4 0,12 mol=>mBaSO4=0,12.233=27,96g

mddA=mddBaCl2+mddH2SO4-mBaSO4

=150+100-27,96=222,04g

C%dd HCl=8,76/222,04.100%=3,945%

C% dd H2SO4=2,94/222,04.100%=1,324%

e) HCl     +NaOH =>NaCl +H2O

0,24 mol=>0,24 mol

H2SO4 +2NaOH =>Na2SO4 + 2H2O

0,03 mol=>0,06 mol

TÔNG nNaOH=0,3 mol

=>V dd NaOH=0,3/2=0,15 lit

PTHH: \(Na_2SO_4+CaCl_2\rightarrow2NaCl+CaSO_4\downarrow\)

Ta có: \(\left\{{}\begin{matrix}n_{Na_2SO_4}=0,1\cdot0,5=0,05\left(mol\right)\\n_{CaCl_2}=0,1\cdot0,4=0,04\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Na₂SO₄ dư

\(\Rightarrow\left\{{}\begin{matrix}n_{CaSO_4}=0,04\left(mol\right)\\n_{NaCl}=0,08\left(mol\right)\\n_{Na_2SO_4\left(dư\right)}=0,01\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CaSO_4}=0,04\cdot136=5,44\left(g\right)\\C_{M_{NaCl}}=\dfrac{0,08}{0,1+0,1}=0,4\left(M\right)\\C_{M_{Na_2SO_4\left(dư\right)}}=\dfrac{0,01}{0,2}=0,05\left(M\right)\end{matrix}\right.\)

nAgNO3= (100.17%)/170=0,1(mol)

nHCl= (300.3,65%)/36,5=0,3(mol)

a) PTHH: AgNO3 + HCl -> AgCl + HNO3

Ta có: 0,1/1 < 0,3/1

=> AgNO3 hết, HCl dư, tính theo nAgNO3

Ta có: nAgCl= nHNO3= nHCl(p.ứ)= nAgNO3= 0,1(mol)

=>m(kt)=mAgCl= 143,5.0,1= 14,35(g)

b) mHCl(dư)= (0,3- 0,1).36,5=7,3(g)

mHNO3= 63.0,1= 6,3(g)

mddsau= mddAgNO3 + mddHCl - mAgCl= 100+300- 14,35= 385,65(g)

=>C%ddHCl(dư)= (7,3/385,65).100= 1,893%

C%ddHNO3= (6,3/385,65).100=1,634%

\(a,PTHH:CuCl_2+2KOH\rightarrow Cu\left(OH\right)_2+2KCl\\ ...0,2......0,4.......0,2........0,4\left(mol\right)\\ b,n_{CuCl_2}=\dfrac{27}{135}=0,2\left(mol\right)\\ m_{Cu\left(OH\right)_2}=0,2\cdot98=19,6\left(g\right)\\ c,m_{KOH}=0,4\cdot56=22,4\left(g\right)\\ m_{dd_{KOH}}=\dfrac{22,4\cdot100\%}{20\%}=112\left(g\right)\\ m_{dd_{KCl}}=m_{CuCl_2}+m_{dd_{KOH}}-m_{Cu\left(OH\right)_2}=27+112-19,6=119,4\left(g\right)\)

\(d,C\%_{dd_{KCl}}=\dfrac{74,5\cdot0,4}{119,4}\cdot100\%\approx24,96\%\)

\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)

PT: \(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)

a, \(n_{HCl}=6n_{Fe_2O_3}=0,6\left(mol\right)\)

\(\Rightarrow C\%_{HCl}=\dfrac{0,6.36,5}{500}.100\%=4,38\%\)

b, \(n_{FeCl_3}=2n_{Fe_2O_3}=0,2\left(mol\right)\)

PT: \(FeCl_3+3KOH\rightarrow3KCl+Fe\left(OH\right)_{3\downarrow}\)

______0,2_______0,6______________0,2 (mol)

\(\Rightarrow C_{M_{KOH}}=\dfrac{0,6}{0,2}=3\left(M\right)\)

\(m_{Fe\left(OH\right)_3}=0,2.107=21,4\left(g\right)\)